尼龙65盐是以等摩尔的戊二酸和己二胺为原料制备的,将其作为单体通过聚合反应可以合成尼龙65。有机溶剂结晶法和水溶液法是制备尼龙65盐的主要方法,尼龙65的制备方法包括界面缩聚、熔融缩聚及其他方法。综述了尼龙65盐以及尼龙65的制备方法,对其发展趋势以及应用前景进行了分析和展望。
Nylon 65 salt is prepared from equimolar glutaric acid and hexamethylene diamine,and it can be used as a monomer to synthesize nylon 65 by polymerization.Organic solvent crystallization method and aqueous solution method are the main methods for preparing nylon 65 salt.The preparation method of nylon 65 includes interfacial polycondensation,melt polycondensation and other methods.The preparation methods of nylon 65 salt and nylon 65 were reviewed.Development trends and application prospects were analyzed and prospected.
[1] Zia A,Ali M.Behavior of fiber reinforced concrete for controlling the rate of cracking in canal-lining[J].Construction and Building Materials,2017,155(1):726-739.
[2] Wang H,Li Y,Zuo Y,et al.Biocompatibility and osteogenesis of biomimetic nano-hydroxyapatite/polyamide composite scaffolds for bone tissue engineering[J].Biomaterials,2007,28(22):3338-3348.
[3] Biffinger J C,Ray R,Little B,et al.Diversifying biological fuel cell designs by use of nanoporous filters[J].Environmental Science & Technology,2007,41(4):1444-1449.
[4] Samad Y A,Komatsu K,Yamashita D,et al.From sewing thread to sensor:nylon fiber strain and pressure sensors[J].Sensors and Actuators B:Chemical,2017,240(1):1083-1090.
[5] 王训遒,李惠萍,蒋登高,等.混合二元酸中戊二酸的分离提纯[J].化工环保,2004,24(2):128-130.
[6] 王飞,王训遒.混合二元酸中戊二酸的分离研究进展[J].河南化工,2016,33(7):7-10.
[7] Carothers W H.Synthetic Fiber:US,2130948[P].1938-07-20.
[8] 郭凯,王海鑫,朱宁,等.一种石墨烯碳纳米管生物基尼龙三元复合材料及其制备方法:中国,105885401[P].2016-08-24.
[9] 郭凯,王海鑫,朱宁,等.一种原位聚合碳纳米管改性尼龙复合材料的制备方法:中国,105669971[P].2016-06-15.
[10] 赵海鹏,张烨,刘伟,等.一种尼龙酸的回收利用方法:中国,108003013[P].2018-05-08.
[11] 王训遒,卢晶晶,张雷.一种尼龙65盐的制备方法:中国,108285532[P].2018-07-17.
[12] Igonin V B,Nikonov V Z,Sokolov L B,et al.Method for preparing heterochain polymers:US,4223105[P].1977-09-16.
[13] Navarro E,Franco L,Subirana J A,et al.Nylon 65 has a unique structure with two directions of hydrogen bonds[J].Macromolecules,1995,28(26):8742-8750.
[14] Morales-Gámez L,Ricart A,Franco L,et al.Study on the brill transition and melt crystallization of nylon 65:a polymer able to adopt a structure with two hydrogen-bonding directions[J].European Polymer Journal,2010,46(10):2063-2077.
[15] Ricart A,Soto D,Franco L,et al.Synchrotron radiation studies on even-odd and odd-even nylons[C]//IOP Conference Series:Materials Science and Engineering,2010:1-7.
[16] Beaman R G,Morgan P W,Koller C R,et al.Interfacial polycondensation.Ⅲ.Polyamides[J].Journal of Polymer Science:Part A:Polymer Chemistry,1959,40(137):329-336.
[17] Cote P,Brisson J.Miscibility of polyamide blends:2.Thermal study of poly(hexame-thyleneisophthalamide)/nylon-n,m blends[J].Macromolecules,1994,27(25):7329-7338.
[18] Rohles G M,Gläser L,Kohlstedt M,et al.A bio-based route to the carbon-5 chemical glutaric acid and to bionylon-6,5 using metabolically engineered corynebacterium glutamicum[J].The Royal Society of Chemistry,2018,20:4662-4674.
[19] Beckham G T,Rorrer N,Vardon D R.Polymers from bio-derived dicarboxylic acids:US,2018282481[P].2018-10-04.
[20] Kiyotsukuri T,Tsutsumi N,Sandan T,et al.Effect of fluorine substituents on the properties of nylon copolymers[J].Journal of Polymer Science:Part A:Polymer Chemistry,1990,28(2):315-322.
[21] Ree K,Tanabe K,Minoura Y.Synthesis of polyamides from diamines and dinitriles with basic catalysts[J].Macromolecular Chemistry and Physics,1979,180(3):603-607.
[22] Panova A,Dicosimo R,Brugel E G,et al.Enzymatic production of macrocyclic amide oligomers:US,20060148044[P].2006-05-18.
[23] Ogata N,Sanui K,Tanaka H,et al.Cellular affinity of polyamides having various functional groups.Ⅰ.Platelet adhesion[J].Journal of Applied Polymer Science,1981,26(7):2293-2303.
[24] 康洪亮,王宇,刘瑞刚,等.一种聚酰胺共混物及其制备方法与应用:中国,107857996[P].2018-03-30.
[25] 王博.一种双组分环氧电子灌封硅胶:中国,104312513[P].2015-01-28.
PDF
